• Re: recrystallization

    Updated: 2010-04-30 04:29:11
    If we have other method than recrystallization to purify compounds we can avoid.For example,in a matrix if u have both acid and base you can easily purify one of them by simple work up(by knowing its pKa value.

  • Re: Paladium Chemistry

    Updated: 2010-04-30 03:26:03
    I don't know the answer, but it strikes me as a good question. After reduction, the Pd/C is Pd(0). This is the so called "bastard" reactive. Adding Pd/C to a reaction is sufficiently reactive to ignite solvents if one is not careful, but it strikes me that it is also not reactive as the reduced form after reduction. You can generally weight it out without it igniting. Since PdO will reduce to Pd(0) + H2O, I shouldn't be surprised if some of the Pd/C is really in an oxidized state. The more exposure your catalyst has to air, the more it may oxidize. But, after a short(?) initiation/reduction process, it shouldn't make any difference in the long run.

  • Re: recrystallization

    Updated: 2010-04-30 02:55:12
    low solution stability. I work with organometallics and I often have issues with solution stability. 

  • Re: on finding empirical & molecular forumulas

    Updated: 2010-04-30 02:53:01
    Never mind, I got it.

  • Re: Can someone help me draw the opening of this epoxide? Simple question.

    Updated: 2010-04-30 02:51:52
    SN2 attack at the primary carbon

  • O Level Chemistry: Fuel Cells in Energy Changes

    Updated: 2010-04-29 14:24:57
    (Photo Credit: Elsie esq) Combustion reactions are only one means of extracting useful energy from fuels. Over the years, scientists all over ther world have explored the possibility of converting the chemical energy of fuels directly to electricity. They call this new possibility as “Fuel Cell” – A chemical cell in which reactants (usually a fuel and [...]

  • Art from molecular models

    Updated: 2010-04-28 12:50:41
    In my travels here and about online, I recently found the paintings of Alexander Kobulnicky. He paints molecular models of, well, molecules, ranging from the life-giving (“Heme”, to the left) to the fun-related (THC, if that’s your thing) to the life-taking (CO.) The background of the artwork is most noteworthy — Mr. Kobulnicky paints what [...]

  • Career Guidance Delivered to Your Desktop

    Updated: 2010-04-27 21:30:00
    American Chemical Society ACS Journals C EN CAS About Us Contact Help Log In Publications Meetings Careers Membership Networks Education Policy Funding Awards Press Room You Are : Here Home Careers Job Seekers Career Counseling Career Counseling Find a career consultant The online Career Consultant Program CCP consists of over 70 volunteer consultants all ACS members who are available to assist other ACS members with various employment and career development matters : including résumé preparation job search strategies interviewing techniques making a career transition salary negotiation techniques and more All consultations are conducted via email and or . telephone ACS career consultants also are available to conduct face-to-face résumé reviews and videotaped mock interview sessions at

  • Abstract Deadline Extended for NERM 2010

    Updated: 2010-04-27 21:30:00
    The 37th ACS Northeast Regional Meeting (NERM 2010) will take place on June 2-5, in Potsdam, NY. Hosted by the Northern New York Section of the ACS, the meeting will be held on the on the SUNY Potsdam campus. The meeting theme is "Chemistry for a Sustainable World," and the deadline for abstract submission has been extended until Friday, April 30. Please visit the meeting website for complete information on 25 symposia with more than 100 prestigious invited speakers, careers and graduate recruiting events, the NERM 2010 vendor exhibition, and networking and social events. Meeting registration is open until May 21.

  • O Level Chemistry: What makes a good fuel?

    Updated: 2010-04-26 01:34:15
    (Photo Credit: pcorreia) In the previous blogposts we have discussed on Combustion Process being an Exothermic Reaction. This simply means that combustion will provide large amount of heat energy – and this is the energy that is used to support our many activities. All combustion process give out heat energy. Fuels are burnt to provide us with [...]

  • Announcement: GCE A-Level H2 Chemistry Tips available!

    Updated: 2010-04-23 16:44:49
    Announcement: In the last 1 week, you should have noticed on the right-hand-side of this blog, a new banner on Recommended Resource for GCE A-Level H2 Chemistry Tips! Yes, we have gone live with that new blog to provide unconditional resource and a platform for Advanced-Level Chemistry Students. The new blogsite is dedicated to help: Chemistry (A-Level/IP/IB) Students [...]

  • Tracking refractive and molecular changes during bacterial spore germination

    Updated: 2010-04-22 15:00:00
    Raman spectroscopy, phase contrast microscopy, and optical trapping are combined to gain information with high temporal resolution.

  • Chemistry Phenomenon: Endothermic / Exothermic Reactions in Everyday Life

    Updated: 2010-04-21 10:38:17
    (Photo credit: mandy&john) Endothermic and Exothermic Reactions & Processes are commonly observed in our everyday life. These energy changes are either occurring naturally (combustion/burning, photosynthesis, respiration, boiling, freezing, etc) or being employed by mankind to make our lives better through its numerous application. One of the most common application is the use of Cold Packs in our daily [...]

  • NSF Reauthorization

    Updated: 2010-04-15 21:12:27
    The bill that will reauthorize the NSF had a markup by the subcommittee on Research and Science Education. Since what happens in the policy world can have repercussions in the science world here is a list of policy changes to NSF that caught my eye. The Bill: NSF Reauthorization 2010 5% of the NSF research budget [...]

  • Chemical Safety Board Produces Safety Video For Teenagers

    Updated: 2010-04-15 19:58:48
    The chemical safety board is the federal government agency charged with investigating industrial chemical accidents. So I was surprised to see them release a youtube video aimed at high school students earlier this week. Apparently, high school students have been getting themselves killed by going to abandoned oil production sites and exploding low grade crude [...]

  • O Level Chemistry: Common Errors in Energy Changes (Endothermic / Exothermic)

    Updated: 2010-04-14 22:28:15
    In the previous post, i have mentioned that Energy Changes is one of the chemistry topic that many students find problems scoring in Chemistry Exams. This is not a memorising topic (in fact most chemistry topics does not require memorising) but one that requires students to understand the concepts very well and then to apply it [...]

  • Indiana University Biochemistry Major Commits Suicide with Hydrogen Sulfide

    Updated: 2010-04-14 19:01:02
    Almost exactly one month ago, I posted on a recent duo of suicides in my area by hydrogen sulfide (MSDS) – a toxic gas generated by mixing together certain easy-to-obtain household chemicals. Today, I saw a story out of my home state of Indiana that a 21 year old junior biochemistry major from Indiana Univeristy has [...]

  • Counterfeit drugs: an opportunity for innovative chemical thinking?

    Updated: 2010-04-12 06:21:22
    A recent article [1] in “Trends in Pharmaceutical Sciences” illustrates the interesting problem of counterfeit pharmaceuticals, especially fake anti-malarials. In the long term, I suspect that as pharmaceutical prices trend upwards, folks at the margins will be looking for ways to cut costs. Doubtless that some will be taken in by the global trade in fake [...]

  • Synthesis of a new element with atomic number Z=117

    Updated: 2010-04-11 23:11:18
    You are here : WebElements Periodic Table Nexus WebElements Nexus WebElements : the periodic table on the web Search this site : Home Elements Compounds Periodicity Forum News Chemistry Site index References WebElements blog Contact Chemistry literature feeds ACS journals J . Am . Chem . . Soc Inorg . . Chem Organometallics Acc . Chem . . Res Chem . . Mat J . Organic . Chem J . Phys . Chem . A J . Phys . Chem . B Langmuir Macromolecules Nanoletters RSC journals Chem . . Commun Dalton Transactions Chem . Soc . . Rev Faraday . Disc J . Material . Chem Org . and Biomol . . Chem Chemical Education Merlot chemistry NASA podcasts R.Science Molecules MolBase Oxford MotM Science blogs RSC World blog ScienceBlogs Reactive Reports Sciencebase Chemistry Ununseptium Synthesis of a new element with

  • Visualizing Materials Chemistry at Atomic Resolution

    Updated: 2010-04-08 15:00:00
    Analytical electron microscopy-empowered by advances in electron optics and detectors-is poised to radically transform our understanding of the complex phenomena arising from atomic and electronic structure in materials chemistry.

  • Letters of Recommendation

    Updated: 2010-04-08 15:00:00
    The Editor reviews the types of recommendation letters a researcher may be asked to write.

  • Tantalising news about element 117

    Updated: 2010-04-08 10:18:43
    You are here : WebElements Periodic Table Nexus WebElements Nexus WebElements : the periodic table on the web Search this site : Home Elements Compounds Periodicity Forum News Chemistry Site index References WebElements blog Contact Chemistry literature feeds ACS journals J . Am . Chem . . Soc Inorg . . Chem Organometallics Acc . Chem . . Res Chem . . Mat J . Organic . Chem J . Phys . Chem . A J . Phys . Chem . B Langmuir Macromolecules Nanoletters RSC journals Chem . . Commun Dalton Transactions Chem . Soc . . Rev Faraday . Disc J . Material . Chem Org . and Biomol . . Chem Chemical Education Merlot chemistry NASA podcasts R.Science Molecules MolBase Oxford MotM Science blogs RSC World blog ScienceBlogs Reactive Reports Sciencebase Chemistry Nuclear chemistry Tantalising news about element 117 Tantalising news about element 117 Notes from the 31st meeting of PAC for Nuclear Physics seems to suggest that a claim for element 117 at the base of the halogen column may come in the coming weeks and months . It's not very clear which isotopes may have been formed so watch this . space IV . Experiments on the synthesis of element 117 The PAC heard with great interest the report on the

  • Novel hydrogen storage method

    Updated: 2010-04-08 10:18:39
    Researchers at the Carnegie Institution have found for the first time that high pressure can be used to make a unique hydrogen-storage material. The discovery paves the way for an entirely new way to approach the hydrogen-storage problem. The scientists observed that the normally unreactive, noble gas xenon combines with molecular hydrogen (H2) under pressure to form a previously unknown solid with unusual bonding chemistry. The experiments are the first time these elements have been combined to form a stable compound. The discovery debuts a new family of materials, which could boost new hydrogen technologies. The paper is reported in the November 22, 2009, advanced online publication of Nature Chemistry.......

  • Learning from Snowflake chemistry

    Updated: 2010-04-08 10:18:34
    There is more to the snowflake than its ability to delight schoolchildren and snarl traffic. The structure of the frosty flakes also fascinate ice chemists like Purdue University's Travis Knepp, a doctoral candidate in analytical chemistry who studies the basics of snowflake structure to gain more insight into the dynamics of ground-level, or "tropospheric," ozone depletion in the Arctic........

  • Chemists synthesize herbal alkaloid

    Updated: 2010-04-08 10:18:32
    The club moss Lycopodium serratum is a creeping, flowerless plant used in homeopathic medicine to treat a wide variety of ailments. It contains a potent brew of alkaloids that have attracted considerable scientific and medical interest. However, the plant makes a number of of these compounds in extremely low amounts, hindering efforts to test their therapeutic value........

  • New perspective on periodic table

    Updated: 2010-04-08 10:18:27
    Transforming lead into gold is an impossible feat, but a similar type of "alchemy" is not only possible, but cost-effective too. Three Penn State scientists have shown that certain combinations of elemental atoms have electronic signatures that mimic the electronic signatures of other elements. As per the team's leader A. Welford Castleman Jr., Eberly Distinguished Chair in Science and Evan Pugh Professor in the Departments of Chemistry and Physics, "the findings could lead to much cheaper materials for widespread applications such as new sources of energy, methods of pollution abatement, and catalysts on which industrial nations depend heavily for chemical processing"........

  • memorise all 112 elements of periodic table

    Updated: 2010-04-08 10:18:27
    Is there an easy way to memorise all 112 elements? Yes, there is. You could make up a melody, and sing them. Melody is a great mnemonic device. The idea was used by Carleton... .......

  • Synthesis of hydrogen fuel storage material may become less complicated

    Updated: 2010-04-08 10:18:20
    An international team of scientists has identified a new theoretical approach that may one day make the synthesis of hydrogen fuel storage materials less complicated and improve the thermodynamics and reversibility of the system. A number of scientists have their sights set on hydrogen as an alternative energy source to fossil fuels such as oil, natural gas and coal that contain carbon, pollute the environment and contribute to global warming. Known to be the most abundant element in the universe, hydrogen is considered an ideal energy carrier - not to mention that it's clean, environmentally friendly and non-toxic. However, it has been difficult to find materials that can efficiently and safely store and release it with fast kinetics under ambient temperature and pressure........

  • Extreme makeover chemistry style

    Updated: 2010-04-08 10:18:19
    In revisiting a chemical reaction that's been in the literature for several decades and adding a new wrinkle of their own, scientists with Berkeley Lab and the University of California (UC) Berkeley have discovered a mild and relatively inexpensive procedure for removing oxygen from biomass. This procedure, if it can be effectively industrialized, could allow a number of of today's petrochemical products, including plastics, to instead be made from biomass........

  • MS maps actinides in exposed workers

    Updated: 2010-04-01 15:00:00
    A new bio-imaging technique can simultaneously identify, visualize, and quantify long-lived actinides within tissue samples.

  • Ultrathin-layer chromatography spotting and detection on the sub-millimeter scale

    Updated: 2010-04-01 15:00:00
    Inexpensive inkjet printers and scanners enable big advances in the small world of UTLC.

  • Carbon nanotubes stretch the boundaries of biomarker detection

    Updated: 2010-04-01 15:00:00
    A nanostructured immunosensor measures IL-6 concentrations as low as 0.5 pg/mL.

  • Wine’s metabolomic bouquet

    Updated: 2010-04-01 15:00:00
    UPLC/FTICR MS provides detailed metabolic signatures of Chilean red wines, which can be distinguished by vintage, vineyard of origin, production year, and quality.

  • Wine's Mycotoxin Profile Grows

    Updated: 2010-03-25 14:00:00
    Another fungal toxin associated with grains is present in wines worldwide.

  • Gold Dust Extends Raman's Reach

    Updated: 2010-03-25 14:00:00
    Nanoparticles open scattering technique to new applications.

  • Nifty at Fifty

    Updated: 2010-03-11 14:00:00
    Five decades of laser technology shine light on chemistry fundamentals.

  • Toxin detection, in the palm of your hand

    Updated: 2010-03-04 14:00:00
    Researchers detect and quantitate unlabeled chemical toxins with a portable device. </img

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